Various factors affecting the emulsification/homogenization effect in actual experiments

Emulsification is influenced by several factors, and the equipment used to prepare emulsions—known as emulsification equipment—is primarily an emulsifying machine. This type of machinery is designed to mix oil and water phases into a stable emulsion. There are three main types of emulsifying machines: emulsifying mixers, colloid mills, and homogenizers. The design, structure, and performance of these machines directly impact the particle size (dispersibility) and overall quality (stability) of the resulting emulsion. In cosmetics manufacturing, agitators or stirrers are commonly used. However, they often produce emulsions with larger, uneven particles and poor stability, which can lead to contamination. Despite this, they are simple to manufacture and cost-effective. With proper design and usage, they can still meet general cosmetic requirements. Colloid mills and homogenizers, on the other hand, offer superior performance in terms of dispersibility and stability. In recent years, advancements like vacuum emulsifiers have significantly improved emulsion quality. Research conducted by Griffin has explored the relationship between different emulsifier types and the resulting particle size distribution. The findings are summarized in the table below: | Emulsifier Type | Particle Size Range (μm) | |----------------------|--------------------------| | 1% Emulsifier | 2–9 | | 5% Emulsifier | 6–9 | | 10% Emulsifier | 1–3 | | Propulsion Stirring | 3–8 | | Turbine Agitator | 2–4 | | Colloid Mill | 4–7 | | Homogenizer | 1–3 | Temperature also plays a critical role in the emulsification process. It greatly affects the quality of the final product, though it isn't strictly limited. If both the oil and water phases are liquid at room temperature, emulsification can be done without heating. However, when high-melting substances are involved, the emulsification temperature must be adjusted accordingly. Factors such as the type of emulsifier and the solubility of the oil and water phases also influence the optimal temperature. It's important that both phases are at similar temperatures, especially when dealing with waxes or high-melting oils. Adding a cold aqueous phase to a hot oil phase can cause waxing or lipid crystal precipitation, leading to an unstable, coarse emulsion. Typically, the temperature during emulsification is kept between 75°C and 85°C. If the oil phase contains high-melting wax, the temperature should be increased. Additionally, if viscosity becomes too high during the process, raising the temperature slightly can help maintain mixing efficiency. The emulsification temperature can also affect the size of the emulsion particles. For example, using an anionic emulsifier like a fatty acid soap, emulsification at 80°C produces particles around 1.8–2.0 μm, while at 60°C, the particle size increases to about 6 μm. Nonionic emulsifiers, however, are less sensitive to temperature changes. Emulsification time is another crucial factor. The duration required depends on the volume ratio of the oil and water phases, their viscosities, the type and amount of emulsifier used, and the emulsification temperature. The goal is to ensure complete emulsification, which is closely related to the efficiency of the equipment. For instance, using a homogenizer at 3000 rpm may only take 3–10 minutes. Finally, stirring speed has a significant impact on the emulsification process. A moderate speed ensures thorough mixing of the oil and water phases. Too low a speed may not achieve proper mixing, while too high a speed can introduce air bubbles, leading to instability. To prevent this, vacuum emulsifiers are often preferred, as they reduce air incorporation and improve overall emulsion quality.

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